Product ID:895 1543,WKG SOL,KODAK X-OMAT ICM F1 FIXER AND REPLENISHER
MSDS Date:01/13/2000
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CLGXD

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

WATER

CAS: 7732-18-5

RTECS: ZC0110000

OSHA PEL NOT RELEVANT

ACGIH TLV: NOT RELEVANT

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

SODIUM THIOSULFATE

CAS: 7772-98-7

RTECS: XN6476000

ACETIC ACID (CERCLA)

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM/15 STEL; 9596

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIUM BISULFITE (CERCLA)

CAS: 10192-30-0

RTECS: WT3595000

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SODIUM BISULFITE

CAS: 7631-90-5

RTECS: VZ2000000

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION:
EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL
HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF
HEATED, SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING.
EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANS IENT IRRITATION.
SKIN: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN
REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH):SODI UM BISULFITE, A4;
NOT CLASSIFIABLE AS A HUMAN CARCINOGEN. - NATIONAL TOXICOLOGY
PROGRAM (NTP):NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
(OSHA): NONE
Effects of Overexposure:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE
A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY
LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO
RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS
MAY EXPERIENCE DIFFICULT BREATHING. EYES: NO SPECIFIC HAZARD KNOWN.
MAY CAUSE TRANSIENT IRRITATION. SKIN: THIS MATERIAL HAS A LOW
POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN
SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST
TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA.

First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY
WITH WATER. GET M EDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH
WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUT H TO AN UNCONSCIOUS PERSON.

Flash Point:NONE
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE (CO2), DRY
CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES
KEEP FROM CONTACT WITH OXIDIZING MATERIALS, HIGHLY OXYGENATED OR
HALOGENATED SOLVENTS, ORGANIC COMPOU NDS CONTAINING REDUCIBLE
FUNCTIONAL GROUPS.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. IF RESPIRATORS ARE USED,
A PROGRAM SHOULD BE I NSTITUTED TO ASSURE COMPLIANCE WITH OSHA
STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT, IMPERVIOUS
GLOVES SHOULD BE WORN.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
THIS MSDS IS FOR ONE PART OF A KIT (895 1543 KODAK X-OMAT ICM F-1 FIXER
& REPLENISHER). THE HMIS SERIAL NUMBERS FOR ALL PARTS OF THIS KIT
(INCLUDING THE ONE FOR THIS MSDS) ARE: CLGXD (WORKING SOL'N) ,
CLGXB, & CLGWY.

HCC:C3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Vapor Pres:68F: 24MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.087
pH:4.3-4.4
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID. COLOR AND ODOR NOT AVAILABLE.
Percent Volatiles by Volume:80- 85 WT

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING
AGENTS, COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS. CONTACT WITH
BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:SULFUR DIOXIDE, AMMONIA, CHLORAMINE.
OXIDES OF NITROGEN, OXIDES OF SULFUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. SINCE EMPTIED CONTAINERS RETAIN
PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS
EMPTIED.

Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY- FISH LC50 MG/L: >100,
DAPHNID EC50 MG/L: >100, ALGAL IC50 MG/L: >100. ORGANICS READILY
DEGRADABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG
POW <1. COD (APPROXIMATE G/L): 90. BOD5 (APPROXIMATE G/L): 70.
POTENTIAL TOXICITY WASTE TREATMENT MICROORGANISMS EC50 (MG/L):
>100. AFTER DILU TION WITH A LARGE AMOUNT OF WATER, FOLLOWED BY
SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE
ADVERSE ENVIRONMENTAL EFFECTS.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 AM AND 5 PM (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: SULFURIC ACID; AMMONIUM THIOSULFAT E, AMMONIUM ACETATE,
AMMONIUM BISULFITE, AS SOURCES OF AQUEOUS AMMONIA.
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.